BLRXS - POTASSIUM FERRICYANIDE, P8131
- MSDS: BLRXS
- Manufacturer: SIGMA CHEMICAL CO
- Product Name: POTASSIUM FERRICYANIDE, P8131
- National Stock Number: 6810-00N021646
Product Identification
Product ID:POTASSIUM FERRICYANIDE, P8131
MSDS Date:06/19/1989
FSC:6810
NIIN:00N021646
MSDS Number: BLRXS
Responsible Party
US
Emergency Phone: 314-771-5765
Info Phone: 800-325-8070
Cage: 21076
Contractor
Telephone: 314-771-5765
Cage: 21076
Ingredients
FERRATE(3-), HEXACYANO-, TRIPOTASSIUM; (POTASSIUM
CAS: 13746-66-2
RTECS: LJ8225000
Hazards
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY BE HARMFUL BY INHALATION,
INGESTION OR SKIN ABSORPTION.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS.
CALL MD. SKIN:FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MIN.
REMOVE CONTAM CLTHG & SHOES & CALL MD. INHAL:REMOVE TO FRESH AIR.
IF BRTHG BE COMES DFCLT, CALL MD. EYES:FLUSH W/COPIOUS AMTS OF
WATER FOR AT LST 15 MIN. ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS
W/FINGER. CALL MD.
Fire Fighting
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Accidental Release
Spill Release Procedures:WEAR NIOSH/MSHA APPRVED RESP, CHEM SFTY
GOGGLES, RUBBER BOOTS & HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN BAG
& HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA &
WASH SPILL SITE AFTER MATL P ICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:CAUTION!AVOID CONTACT AND INHALATION.
LIGHT SENSITIVE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
Exposure Controls
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
WASTE DISP METH:ANY SOLIDS FOR BURIAL IN CHEM LANDFILL. PRECIP ANY HVY
METALS BY ADDN OF SULFIDE & ISOLATE FOR BURIAL. ADDNL EQUIVALENTS
OF HYPOCHLORITE MAY BE NEEDED IF METAL CAN BE OXIDIZED TO HIGHE R
VALENCE STATE. FOR METAL CARBONYLS, RXN SHOULD BE CARRIED OUT UNDER
NITROGEN. OBSERVE ALL FED, STATE & LOC LAWS.
Chemical Properties
HCC:N1
Spec Gravity:1.89
Solubility in Water:SOLUBLE
Appearance and Odor:ORANGE CRYSTALLINE POWDER
Stability
Stability Indicator/Materials to Avoid:YES
ACIDS, AMMONIA. AVOID CONTACT WITH SODIUM NITRITE & CHROMIUM TRIOXIDE.
Stability Condition to Avoid:PROTECT FROM LIGHT. DECOMPOSES ON CONTACT
WITH ACID OR ACID FUMES TO EMIT FUMES OF CYANIDES.
Hazardous Decomposition Products:TOXIC FUMES OF:HYDROGEN CYANIDE, CO,
CO2 & NOX.
Disposal
Waste Disposal Methods:TREAT A DILUTE BASIC SOLN (PH 10-11) OF MATL
W/50% EXCESS OF COMMERCIAL LAUNDRY BLEACH. CONTROL TEMP BY ADDN
RATE OF BLEACH & ADJUST PH IF NEC. LET STAND OVERNIGHT. CAUTIOUSLY
ADJUST SOLN TO PH 7. VIG OROUS EVOLUTION OF GAS MAY OCCUR. FILTER
(SUPDAT)
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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.